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2-Methyl-N-o-tolyl-benzamide.

ABSTRACT: In the title compound, C(15)H(15)NO, the C-N-C(O)-C amide unit is planar (r.m.s. deviation = 0.003?Å) and subtends dihedral angles of 44.71?(5) and 43.33?(5)° with the two o-tolyl rings. These aromatic rings are inclined at 4.94?(7)° to one another. The ortho-methyl groups of the two tolyl rings are anti to one another. In the crystal structure, N-H?O hydrogen bonds augmented by C-H?? inter-actions link the mol-ecules in a head-to-head fashion into chains along a. Independent chains pack in a herringbone pattern along c.

SUBMITTER: Saeed A 

PROVIDER: S-EPMC2980266 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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2-Methyl-N-o-tolyl-benzamide.

Saeed Aamer A   Khera Rasheed Ahmad RA   Siddiq Muhammad M   Simpson Jim J  

Acta crystallographica. Section E, Structure reports online 20091204 Pt 1

In the title compound, C(15)H(15)NO, the C-N-C(O)-C amide unit is planar (r.m.s. deviation = 0.003 Å) and subtends dihedral angles of 44.71 (5) and 43.33 (5)° with the two o-tolyl rings. These aromatic rings are inclined at 4.94 (7)° to one another. The ortho-methyl groups of the two tolyl rings are anti to one another. In the crystal structure, N-H⋯O hydrogen bonds augmented by C-H⋯π inter-actions link the mol-ecules in a head-to-head fashion into chains along a. Independent chains pack in a he  ...[more]