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[?-N,N,N',N'-Tetra-kis(2-pyridyl-meth-yl)butane-1,4-diamine]-bis-[dinitratocadmium(II)].

ABSTRACT: The title dinuclear cadmium complex, [Cd(2)(NO(3))(4)(C(28)H(32)N(6))], is located on an inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl-amine group of the ligand via the N atoms in a meridional fashion and two O atoms of the nitrate ligands with short Cd-O distances. The coordination is completed by two loosely bound O atoms of the nitrate ligands.

SUBMITTER: Bartholoma M

PROVIDER: S-EPMC2983215 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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[μ-N,N,N',N'-Tetra-kis(2-pyridyl-meth-yl)butane-1,4-diamine]-bis-[dinitratocadmium(II)].

Bartholomä Mark M Cheung Hoi H Zubieta Jon J

Acta crystallographica. Section E, Structure reports online 20100904 Pt 10

The title dinuclear cadmium complex, [Cd(2)(NO(3))(4)(C(28)H(32)N(6))], is located on an inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl-amine group of the ligand via the N atoms in a meridional fashion and two O atoms of the nitrate ligands with short Cd-O distances. The coordination is completed by two loosely bound O atoms of the nitrate ligands. ...[more]

PMID: 21587358

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[?-N,N,N',N'-Tetra-kis(2-pyridyl-meth-yl)butane-1,4-diamine]-bis-[dibromidocopper(II)].

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1,4-Dichloro-2,3-bis-(chloro-meth-yl)butane.

Project description:The title compound, C6H10Cl4, adopts a geometric arrangement with two C-Cl bonds anti-periplanar to C-H bonds and the other two anti-periplanar to C-C bonds. While minimising steric replusion, this arrangement still gives rise to some intramolecular C-H?Cl contacts. In the crystal, mol-ecules are connected into a three-dimensional architecture via further C-H?Cl contacts.

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Crystal structure of 1,4-bis-[5-(2-meth-oxy-phen-yl)-2H-tetra-zol-2-yl]butane.

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