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[(Z)-O-Ethyl N-phenyl-thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I): a monoclinic polymorph.

ABSTRACT: The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P) polymorph [Hall et al. (1993 ?). Aust. J. Chem.46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43?(3)°], with the distortion due in part to a close intra-molecular Au?O contact [3.036?(2)?Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H?? inter-actions.

SUBMITTER: Tadbuppa PP 

PROVIDER: S-EPMC2983808 | biostudies-other | 2010 Mar

REPOSITORIES: biostudies-other

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[(Z)-O-Ethyl N-phenyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I): a monoclinic polymorph.

Tadbuppa Primjira P PP   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20100313 Pt 4

The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P) polymorph [Hall et al. (1993 ▶). Aust. J. Chem.46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.036 (2) Å]. In the crystal structure, mol-ecules are arranged into supra-mo  ...[more]

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