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{1,1'-[2,2-Dimethyl-propane-1,3-diylbis(nitrilo-methyl-idyne)]di-2-naphtholato}nickel(II).

ABSTRACT: In the title Schiff base complex, [Ni(C(27)H(24)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the two aromatic rings is 6.16?(6)°. In the crystal, pairs of inter-molecular weak C-H?O hydrogen bonds link neighboring mol-ecules into a chain along the a axis. The crystal structure is further stabilized by two inter-molecular ?-? inter-actions with centroid-centroid distances of 3.7252?(13) and 3.8323?(13)?Å.

SUBMITTER: Kargar H

PROVIDER: S-EPMC2983828 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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{1,1'-[2,2-Dimethyl-propane-1,3-diylbis(nitrilo-methyl-idyne)]di-2-naphtholato}nickel(II).

Kargar Hadi H Kia Reza R Khan Islam Ullah IU Zare Karim K

Acta crystallographica. Section E, Structure reports online 20100303 Pt 4

In the title Schiff base complex, [Ni(C(27)H(24)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the two aromatic rings is 6.16 (6)°. In the crystal, pairs of inter-molecular weak C-H⋯O hydrogen bonds link neighboring mol-ecules into a chain along the a axis. The crystal structure is further stabilized by two inter-molecular π-π inter-actions with centroid-centroid distances of 3.7252 (13) and 3.8323 (13) Å. ...[more]

PMID: 21580475

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