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Bis(acetato-?O,O')diphen-yl(pyridine-?N)tin(IV).

ABSTRACT: The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(2)H(3)O(2))(2)(C(5)H(5)N)], contains two crystallography independent mol-ecules. In both mol-ecules, the Sn(IV) atom is seven-coordinated in a distorted penta-gonal-bipyramidal geometry with the two phenyl groups in axial positions. The two mol-ecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54?(15) and 60.11?(14)° in the two mol-ecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6?(2) and 41.77?(13)° in the two mol-ecules.

SUBMITTER: Khaledi H

PROVIDER: S-EPMC2983829 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Bis(acetato-κO,O')diphen-yl(pyridine-κN)tin(IV).

Khaledi Hamid H Mohd Ali Hapipah H Abdulla Mahmood A MA

Acta crystallographica. Section E, Structure reports online 20100303 Pt 4

The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(2)H(3)O(2))(2)(C(5)H(5)N)], contains two crystallography independent mol-ecules. In both mol-ecules, the Sn(IV) atom is seven-coordinated in a distorted penta-gonal-bipyramidal geometry with the two phenyl groups in axial positions. The two mol-ecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15) and 60.11 (14)° in the two mol-ecules while the dihedral angle ...[more]

PMID: 21580466

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