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3-Chloro-N-(4-hydr-oxy-3-methoxy-benz-yl)-2,2-dimethyl-propanamide.

ABSTRACT: In the mol-ecular structure of the title compound, C(13)H(18)ClNO(3), the amide group is nearly perpendicular to the benzene ring, making a dihedral angle of 85.66?(9)°. The C=O bond distance of 1.242?(3)?Å and the C-N bond distance of 1.333?(3)?Å suggest electron delocalization in the amide fragment. Inter-molecular O-H?O and N-H?O hydrogen bonding helps to stabilize the crystal structure.

SUBMITTER: Huang YL

PROVIDER: S-EPMC2983855 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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3-Chloro-N-(4-hydr-oxy-3-methoxy-benz-yl)-2,2-dimethyl-propanamide.

Huang Yan-Lan YL Wang Wen-Long WL Shan Shang S

Acta crystallographica. Section E, Structure reports online 20100320 Pt 4

In the mol-ecular structure of the title compound, C(13)H(18)ClNO(3), the amide group is nearly perpendicular to the benzene ring, making a dihedral angle of 85.66 (9)°. The C=O bond distance of 1.242 (3) Å and the C-N bond distance of 1.333 (3) Å suggest electron delocalization in the amide fragment. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonding helps to stabilize the crystal structure. ...[more]

PMID: 21580696

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