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Bis[diamminesilver(I)] 5-nitro-iso-phthalate monohydrate.

ABSTRACT: In the title compound, [Ag(NH(3))(2)](2)(C(8)H(3)NO(6))·H(2)O, the cations have an almost linear coordination geometry with two ammine ligands and inter-act with the water mol-ecules [Ag?O(water) = 2.725?(4) and 2.985?(4)?Å]. In the crystal, N-H?O and O-H?O hydrogen bonds, combined with weak (lone pair)?? [O?centroid distance = 3.401?(4)?Å] and ?-? stacking [centroid-centroid distance = 3.975?(3)?Å] inter-actions, stabilize the three-dimensional supra-molecular network.

SUBMITTER: Sun D

PROVIDER: S-EPMC2983872 | biostudies-other | 2010 Mar

REPOSITORIES: biostudies-other

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Bis[diamminesilver(I)] 5-nitro-iso-phthalate monohydrate.

Sun Di D Luo Geng-Geng GG Zhang Na N Huang Rong-Bin RB

Acta crystallographica. Section E, Structure reports online 20100313 Pt 4

In the title compound, [Ag(NH(3))(2)](2)(C(8)H(3)NO(6))·H(2)O, the cations have an almost linear coordination geometry with two ammine ligands and inter-act with the water mol-ecules [Ag⋯O(water) = 2.725 (4) and 2.985 (4) Å]. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds, combined with weak (lone pair)⋯π [O⋯centroid distance = 3.401 (4) Å] and π-π stacking [centroid-centroid distance = 3.975 (3) Å] inter-actions, stabilize the three-dimensional supra-molecular network. ...[more]

PMID: 21580507

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