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Catena-Poly[[[bis-(2,2'-bipyridine)manganese(II)]-?(4)-3,3'-sulfanediyldipropionato] bis-(perchlorate)].

ABSTRACT: The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2'-bipyridine ligands and two O atoms of two different 3,3'-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions. The two carboxyl-ate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional chains extending along [010].

SUBMITTER: Yong L 

PROVIDER: S-EPMC2983876 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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catena-Poly[[[bis-(2,2'-bipyridine)manganese(II)]-μ(4)-3,3'-sulfanediyldipropionato] bis-(perchlorate)].

Yong Li L  

Acta crystallographica. Section E, Structure reports online 20100306 Pt 4

The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2'-bipyridine ligands and two O atoms of two different 3,3'-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions. The two carboxyl-ate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional  ...[more]

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