Unknown

Dataset Information

0

Triaqua-(1,10-phenanthroline-2,9-dicarboxyl-ato)cobalt(II) dihydrate.

ABSTRACT: The title compound, [Co(C(14)H(6)N(2)O(4))(H(2)O)(3)]·2H(2)O, has two-fold crystallographic symmetry. The Co(II) atom is in a distorted penta-gonal-bipyramidal coordination environment with two N atoms and two O atoms from a tetradentate 1,10-phenanthroline-2,9-dicarboxyl-ate ligand and one O atom from a water mol-ecule forming the penta-gonal plane, and two O atoms from two water mol-ecules occupying axial positions. In the crystal, adjacent mol-ecules are linked by O-H?O hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Shi ZF 

PROVIDER: S-EPMC2983888 | biostudies-other | 2010 Mar

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Triaqua-(1,10-phenanthroline-2,9-dicarboxyl-ato)cobalt(II) dihydrate.

Shi Zi-Fa ZF   Gao Zhu-Qing ZQ   Gu Jin-Zhong JZ  

Acta crystallographica. Section E, Structure reports online 20100306 Pt 4

The title compound, [Co(C(14)H(6)N(2)O(4))(H(2)O)(3)]·2H(2)O, has two-fold crystallographic symmetry. The Co(II) atom is in a distorted penta-gonal-bipyramidal coordination environment with two N atoms and two O atoms from a tetradentate 1,10-phenanthroline-2,9-dicarboxyl-ate ligand and one O atom from a water mol-ecule forming the penta-gonal plane, and two O atoms from two water mol-ecules occupying axial positions. In the crystal, adjacent mol-ecules are linked by O-H⋯O hydrogen bonds, formin  ...[more]

Similar Datasets

Unknown Triaqua-(cyclo-hex-4-ene-1,2-dicarboxyl-ato-?O(1))(1,10-phenanthroline-?(2)N,N')cobalt(II).
| S-EPMC3515127 | biostudies-literature
Unknown (5,5'-Dicarboxy-biphenyl-2,2'-dicarboxyl-ato-?O,O)bis-(1,10-phenanthroline-?N,N')cobalt(II) dihydrate.
| S-EPMC2961536 | biostudies-literature
Unknown (2,9-Dimethyl-1,10-phenanthroline)(4-hydroxy-pyridine-2,6-dicarboxyl-ato)copper(II) trihydrate.
| S-EPMC2969473 | biostudies-literature
Unknown Dichlorido(2,9-dimethyl-1,10-phenanthroline-?N,N')cobalt(II).
| S-EPMC2983147 | biostudies-literature
Unknown Triaqua-chlorido(1,10-phenanthroline-?N,N')cobalt(II) chloride monohydrate.
| S-EPMC2968016 | biostudies-literature
Unknown Tetra-aqua-bis(1,10-phenanthroline)bis-[?(2)-1H-pyrazole-3,5-dicarboxyl-ato(3-)]tricopper(II) dihydrate.
| S-EPMC2979153 | biostudies-literature
Unknown Bis(benzoato-?O,O')(2,9-dimethyl-1,10-phenanthroline-?N,N')cobalt(II).
| S-EPMC2960282 | biostudies-literature
Unknown (?-Butane-1,2,3,4-tetra-carboxyl-ato)bis-[triaqua-(1,10-phenanthroline)nickel(II)] hexa-hydrate.
| S-EPMC3011463 | biostudies-literature
Unknown catena-Poly[[aqua-(pyrazino[2,3-f][1,10]phenanthroline-?N,N)cobalt(II)]-?-pyrazine-2,3-dicarboxyl-ato-?NO:O].
| S-EPMC2960716 | biostudies-literature
Unknown catena-Poly[[[aqua-(1,10-phenanthroline-κN,N')cadmium(II)]-μ-pyridine-2,3-dicarboxyl-ato-κN,O:O,O] dihydrate].
| S-EPMC2959933 | biostudies-literature