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Dimethyl 4-(3-hydroxy-phen-yl)-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxyl-ate.

ABSTRACT: The 1,4-dihydro-pyridine ring in the title compound, C(17)H(19)NO(5), has a flattened-boat conformation, and the benzene ring is almost orthogonal to it [dihedral angle = 82.98?(12)°]. The hydr-oxy group is disordered over two positions in a 0.780?(4):0.220?(4) ratio. In the crystal, hydrogen-bonding inter-actions of the type N(a)-H?O(c) and O(h)-H?O(c) (a = amine, c = carbonyl and h = hydr-oxy) link the mol-ecules into a three-dimensional network.

SUBMITTER: Rajesh K

PROVIDER: S-EPMC2983893 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Dimethyl 4-(3-hydroxy-phen-yl)-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxyl-ate.

Rajesh K K Vijayakumar V V Narasimhamurthy T T Suresh J J Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100331 Pt 4

The 1,4-dihydro-pyridine ring in the title compound, C(17)H(19)NO(5), has a flattened-boat conformation, and the benzene ring is almost orthogonal to it [dihedral angle = 82.98 (12)°]. The hydr-oxy group is disordered over two positions in a 0.780 (4):0.220 (4) ratio. In the crystal, hydrogen-bonding inter-actions of the type N(a)-H⋯O(c) and O(h)-H⋯O(c) (a = amine, c = carbonyl and h = hydr-oxy) link the mol-ecules into a three-dimensional network. ...[more]

PMID: 21580781

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Dimethyl 2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxyl-ate.

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