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2-Ferrocenyl-N-(6-methyl-2-pyrid-yl)benzamide.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methyl-pyridine, crystallizes with two dissimilar mol-ecules in the asymmetric unit. In one mol-ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, mol-ecules aggregate into dimers via cyclic, asymmetric N-H?N inter-actions with graph set R(2) (2)(8), and are further augmented via intra-molecular C-H?O=C and inter-dimer C-H??(arene) inter-actions. Dimers are linked into chains along the [102] direction via weak C-H?O hydrogen bonds.

SUBMITTER: Gallagher JF

PROVIDER: S-EPMC2983907 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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2-Ferrocenyl-N-(6-methyl-2-pyrid-yl)benzamide.

Gallagher John F JF Alley Steven S Lough Alan J AJ

Acta crystallographica. Section E, Structure reports online 20100313 Pt 4

The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methyl-pyridine, crystallizes with two dissimilar mol-ecules in the asymmetric unit. In one mol-ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, mol-ecules aggregate into dimers via cyclic, asymmetric N-H⋯N inter-actions with graph set R(2) (2)(8), and are furt ...[more]

PMID: 21580500

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