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N-(2,6-Dimethyl-phen-yl)-3-methyl-benzamide.

ABSTRACT: In the mol-ecular structure of the title compound, C(16)H(17)NO, the N-H and C=O bonds are anti to each other. The two aromatic rings make a dihedral angle of 73.3?(1)°. In the crystal, inter-molecular N-H?O hydrogen bonds connect the mol-ecules into C(4) chains running along the c axis.

SUBMITTER: Rodrigues VZ

PROVIDER: S-EPMC2984014 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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N-(2,6-Dimethyl-phen-yl)-3-methyl-benzamide.

Rodrigues Vinola Z VZ Tokarčík Miroslav M Gowda B Thimme BT Kožíšek Jozef J

Acta crystallographica. Section E, Structure reports online 20100331 Pt 4

In the mol-ecular structure of the title compound, C(16)H(17)NO, the N-H and C=O bonds are anti to each other. The two aromatic rings make a dihedral angle of 73.3 (1)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds connect the mol-ecules into C(4) chains running along the c axis. ...[more]

PMID: 21580787

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N-(2,6-Dimethyl-phen-yl)-4-methyl-benzamide.

Project description:In the mol-ecular structure of the title compound, C(16)H(17)NO, the two aromatic rings are close to orthogonal to each other [dihedral angle 78.8?(1)°], while the central -NH-C(=O)- amide core is nearly coplanar with the benzoyl ring, forming a dihedral angle of 3.5?(2)°. Inter-molecular N-H?O hydrogen bonds in the crystal structure link the mol-ecules into infinite chains running along the c axis of the crystal, and a C-H?O interaction also occurs.

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N-(2,6-Dimethyl-phen-yl)benzamide.

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N-(2,4-Dimethyl-phen-yl)-4-methyl-benzamide.

Project description:In the mol-ecule of the title compound, C(16)H(17)NO, the N-H and C=O bonds are anti to each other and the two benzene rings form a dihedral angle of 75.8?(1)°. The amide group is twisted by 28.1?(3) and 76.3?(2)° out of the planes of the 4-methyl-phenyl and 2,4-dimethyl-phenyl rings, respectively. In the crystal, inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the c axis. The crystal studied was hemihedrally twinned with a twin law resulting from a twofold rotation about the a axis.

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Project description:The title compound, C(16)H(17)NO, crystallizes with two mol-ecules in the asymmetric unit. The conformation of the N-H bond is anti to the meta-methyl substituent in the aniline ring in the first mol-ecule and syn in the second mol-ecule. The dihedral angles between the two benzene rings are 52.6?(1) and 10.5?(1)° in the first and second mol-ecules, respectively. Inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the b axis of the crystal.

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