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Catena-Poly[copper(II)-bis-(?-3-cyano-2-hydroxy-propionato)-?N:O,O;?O,O:N-copper(II)].

ABSTRACT: The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxy-propionate ligands and two hydr-oxy O atoms and two carboxyl-ate O atom from two other two ligands in a distorted octa-hedral geometry. Inter-molecular C-H?O and O-H?O hydrogen bonds connect the chains into a three-dimensional structure.

SUBMITTER: Wang JD

PROVIDER: S-EPMC2984082 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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catena-Poly[copper(II)-bis-(μ-3-cyano-2-hydroxy-propionato)-κN:O,O;κO,O:N-copper(II)].

Wang Ji-Dong JD Han Shu-Min SM

Acta crystallographica. Section E, Structure reports online 20100303 Pt 4

The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxy-propionate ligands and two hydr-oxy O atoms and two carboxyl-ate O atom from two other two ligands in a distorted octa-hedral geometry. Inter-molecular C-H⋯O and O-H⋯O hydrogen bonds connect the chains into a three-dimensional structure. ...[more]

PMID: 21580472

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