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Hexa-kis-(dimethyl sulfoxide-?O)thallium(III) trinitrate.

ABSTRACT: The title compound, [Tl(C(2)H(6)OS)(6)](NO(3))(3), consists of six dimethyl sulfoxide (DMSO) mol-ecules coordinated to a Tl(III) atom, which lies on a axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa-hedral, defined by six O atoms of the DMSO mol-ecules. In the crystal structure, C-H?O hydrogen bonds are observed. One of the nitrate groups exhibits half-occupation.

SUBMITTER: Ghadermazi M

PROVIDER: S-EPMC3006801 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Hexa-kis-(dimethyl sulfoxide-κO)thallium(III) trinitrate.

Ghadermazi Mohammad M Manteghi Faranak F

Acta crystallographica. Section E, Structure reports online 20100618 Pt 7

The title compound, [Tl(C(2)H(6)OS)(6)](NO(3))(3), consists of six dimethyl sulfoxide (DMSO) mol-ecules coordinated to a Tl(III) atom, which lies on a axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa-hedral, defined by six O atoms of the DMSO mol-ecules. In the crystal structure, C-H⋯O hydrogen bonds are observed. One of the nitrate groups exhibits half-occupation. ...[more]

PMID: 21587730

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