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9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca-borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9)).


ABSTRACT: The asymmetric unit of the title compound, C(6)H(16)B(10), contains one mol-ecule that is close to possessing a non-crystallographic plane of mirror symmetry in the space group Pna2(1). The orientation of the mol-ecules in the ortho-rhom-bic cell shows that the structure can not be described in the space group Pnma, which has the same systematic absence conditions. The long inner-cluster C-C distance of 1.510?(5)?Å is typical for {1,2-Me(2)-closo-1,2-C(2)B(10)} derivatives.

SUBMITTER: Finze M 

PROVIDER: S-EPMC3006814 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca-borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9)).

Finze Maik M   Reiss Guido J GJ  

Acta crystallographica. Section E, Structure reports online 20100618 Pt 7


The asymmetric unit of the title compound, C(6)H(16)B(10), contains one mol-ecule that is close to possessing a non-crystallographic plane of mirror symmetry in the space group Pna2(1). The orientation of the mol-ecules in the ortho-rhom-bic cell shows that the structure can not be described in the space group Pnma, which has the same systematic absence conditions. The long inner-cluster C-C distance of 1.510 (5) Å is typical for {1,2-Me(2)-closo-1,2-C(2)B(10)} derivatives. ...[more]

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