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Fac-Tris(4-amino-benzohydroxamato)iron(III) ethanol solvate.

ABSTRACT: In the structure of the title compound, [Fe(C(7)H(7)N(2)O(2))(3)]·CH(3)CH(2)OH, the Fe(III) atom is in a distorted octa-hedral O(6) environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl C atom of the ethanol solvent mol-ecule is disordered over two positions with occupancies of 0.626?(13) and 0.374?(13), respectively. The cocrystallized ethanol mol-ecule is hydrogen bonded to one of the hydroxamate O atoms. O-H?O and N-H?O inter-actions generate infinite three-dimensional networks along [100], [010] and [001].

SUBMITTER: Alagha AB

PROVIDER: S-EPMC3006831 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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fac-Tris(4-amino-benzohydroxamato)iron(III) ethanol solvate.

Alagha Ahmed B M AB Gaynor Declan D Müller-Bunz Helge H Nolan Kevin B KB Parthasarathi Laavanya L

Acta crystallographica. Section E, Structure reports online 20100626 Pt 7

In the structure of the title compound, [Fe(C(7)H(7)N(2)O(2))(3)]·CH(3)CH(2)OH, the Fe(III) atom is in a distorted octa-hedral O(6) environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl C atom of the ethanol solvent mol-ecule is disordered over two positions with occupancies of 0.626 (13) and 0.374 (13), respectively. The cocrystallized ethanol mol-ecule is hydrogen bonded to o ...[more]

PMID: 21587762

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