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(4-Carb-oxy-2-sulfonato-benzoato-?O,O)bis-(1,10-phenanthroline-?N,N')manganese(II).


ABSTRACT: In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carb-oxy-2-sulfonato-benzoate anion and two phenathroline (phen) ligands in a distorted octa-hedral MnN(4)O(2) geometry. The benzene ring of the 4-carb-oxy-2-sulfonato-benzoate anion is twisted with respect to the two phen ring systems at dihedral angles of 66.38?(9) and 53.56?(9)°. In the crystal, inter-molecular O-H?O and C-H?O hydrogen bonding links the mol-ecules into chains running parallel to [100]. Inter-molecular ?-? stacking is also observed between parallel phen ring systems, the face-to-face distance being 3.432?(6)?Å.

SUBMITTER: Wu QF 

PROVIDER: S-EPMC3006856 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(4-Carb-oxy-2-sulfonato-benzoato-κO,O)bis-(1,10-phenanthroline-κN,N')manganese(II).

Wu Qiong-Fang QF   Li Ming-Xing MX  

Acta crystallographica. Section E, Structure reports online 20100626 Pt 7


In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carb-oxy-2-sulfonato-benzoate anion and two phenathroline (phen) ligands in a distorted octa-hedral MnN(4)O(2) geometry. The benzene ring of the 4-carb-oxy-2-sulfonato-benzoate anion is twisted with respect to the two phen ring systems at dihedral angles of 66.38 (9) and 53.56 (9)°. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonding links the mol-ecules into chains running parallel to  ...[more]

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