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Hexaaqua-zinc(II) bis-(2,4,5-tricarboxybenzoate) 4,5-diaza-fluoren-9-one disolvate dihydrate.


ABSTRACT: The asymmetric unit of the title complex, [Zn(H(2)O)(6)](C(10)H(5)O(8))(2)·2C(11)H(6)N(2)O·2H(2)O, contains one half of the complex cation with the Zn(II) ion located on an inversion center, a monovalent 2,4,5-tricarboxybenzoate (1,2,4,5-BTC) counter-anion, a 4,5-diaza-fluoren-9-one (DAFO) mol-ecule and an uncoordinated water mol-ecule. In the crystal structure, O-H?O and O-H?N hydrogen bonds link the cations, anions and water mol-ecules into a three-dimensional network.

SUBMITTER: Yang GF 

PROVIDER: S-EPMC3006871 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Hexaaqua-zinc(II) bis-(2,4,5-tricarboxybenzoate) 4,5-diaza-fluoren-9-one disolvate dihydrate.

Yang Gui-Fu GF   Zhao Ya-Hui YH  

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7


The asymmetric unit of the title complex, [Zn(H(2)O)(6)](C(10)H(5)O(8))(2)·2C(11)H(6)N(2)O·2H(2)O, contains one half of the complex cation with the Zn(II) ion located on an inversion center, a monovalent 2,4,5-tricarboxybenzoate (1,2,4,5-BTC) counter-anion, a 4,5-diaza-fluoren-9-one (DAFO) mol-ecule and an uncoordinated water mol-ecule. In the crystal structure, O-H⋯O and O-H⋯N hydrogen bonds link the cations, anions and water mol-ecules into a three-dimensional network. ...[more]

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