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(7E)-5-Benzyl-7-(2-chloro-benzyl-idene)-3-(2-chloro-phen-yl)-2-phenyl-3,3a,4,5,6,7-hexa-hydro-2H-pyrazolo-[4,3-c]pyridine.

ABSTRACT: In the title 2H-pyrazolo-[4,3-c]pyridine derivative, C(32)H(27)Cl(2)N(3), the dihydro-pyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intra-molecular C-H?Cl contacts are observed. The crystal packing is characterized by dimeric C-Cl?? inter-actions involving the 5-benzyl ring, with Cl?centroid and closest atomic Cl?? distances of 3.778?(2) and 3.366?(4)?Å, respectively.

SUBMITTER: Karthikeyan NS

PROVIDER: S-EPMC3006872 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(7E)-5-Benzyl-7-(2-chloro-benzyl-idene)-3-(2-chloro-phen-yl)-2-phenyl-3,3a,4,5,6,7-hexa-hydro-2H-pyrazolo-[4,3-c]pyridine.

Karthikeyan N S NS Mahesh B Uma BU Sathiyanarayanan K K Raghavaiah P P Rathore R S RS

Acta crystallographica. Section E, Structure reports online 20100623 Pt 7

In the title 2H-pyrazolo-[4,3-c]pyridine derivative, C(32)H(27)Cl(2)N(3), the dihydro-pyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intra-molecular C-H⋯Cl contacts are observed. The crystal packing is characterized by dimeric C-Cl⋯π inter-actions involving the 5-benzyl ring, with Cl⋯centroid and closest atomic Cl⋯π distances of 3.778 (2) and 3.366 (4) Å, respectively. ...[more]

PMID: 21587951

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