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(E)-2-(2-Furylmethyl-idene)-2,3-dihydro-1H-pyrrolizin-1-one.

ABSTRACT: The title compound, C(12)H(9)NO(2), was prepared by an Aldol reaction of furfuraldehyde with 2,3-dihydro-1H-pyrrolizin-1-one. The mol-ecule is almost planar, with an r.m.s. deviation of 0.045?Å, excluding the methyl-ene H atoms. In the crystal structure, mol-ecules are linked via weak inter-molecular C-H?O hydrogen bonding and aromatic ?-? stacking [centroid-centroid distance = 3.6151?(9)?Å].

SUBMITTER: Ali Y

PROVIDER: S-EPMC3006878 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(E)-2-(2-Furylmethyl-idene)-2,3-dihydro-1H-pyrrolizin-1-one.

Ali Yousaf Y Yu Peng P Hua Erbing E Rui Guo G Qi Sun S

Acta crystallographica. Section E, Structure reports online 20100605 Pt 7

The title compound, C(12)H(9)NO(2), was prepared by an Aldol reaction of furfuraldehyde with 2,3-dihydro-1H-pyrrolizin-1-one. The mol-ecule is almost planar, with an r.m.s. deviation of 0.045 Å, excluding the methyl-ene H atoms. In the crystal structure, mol-ecules are linked via weak inter-molecular C-H⋯O hydrogen bonding and aromatic π-π stacking [centroid-centroid distance = 3.6151 (9) Å]. ...[more]

PMID: 21587819

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