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Dicylopenta-dien-yl[4-(4-vinyl-benz-yloxy)pyridine-2,6-dicarboxyl-ato]titanium(IV) monohydrate.

ABSTRACT: The title compound, [Ti(C(5)H(5))(2)(C(16)H(11)NO(5))]·H(2)O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxyl-ate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water mol-ecule forms strong O-H?O hydrogen bonds with the carboxyl-ate O atoms of the Ti complex, which play an important role in the connection of adjacent mol-ecules. In addition, weak inter-molecular C-H?O hydrogen bonds also contribute to the crystal packing arrangement.

SUBMITTER: Zhu F

PROVIDER: S-EPMC3006885 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Dicylopenta-dien-yl[4-(4-vinyl-benz-yloxy)pyridine-2,6-dicarboxyl-ato]titanium(IV) monohydrate.

Zhu Fanghua F Qin Yuancheng Y Lei Jiehong J Zhang Lin L Yin Qiang Q

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

The title compound, [Ti(C(5)H(5))(2)(C(16)H(11)NO(5))]·H(2)O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxyl-ate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water mol-ecule forms strong O-H⋯O hydrogen bonds with the carboxyl-ate O atoms of the Ti complex, which play an important role in the connection of adjacent mol-ecul ...[more]

PMID: 21587700

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