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Poly[(?(3)-4-amino-benzene-sulfonato-?N:O:O)(triphenyl-phosphine-?P)silver(I)].

ABSTRACT: In the title 1:1 silver 4-amino-benzene-sulfonate adduct with triphenyl-phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon-ate -SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra-hedral coordination. In the crystal, adjacent binuclear mol-ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.

SUBMITTER: Sadeghi O

PROVIDER: S-EPMC3006886 | biostudies-other | 2010 Jun

REPOSITORIES: biostudies-other

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Poly[(μ(3)-4-amino-benzene-sulfonato-κN:O:O)(triphenyl-phosphine-κP)silver(I)].

Sadeghi Omid O Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100626 Pt 7

In the title 1:1 silver 4-amino-benzene-sulfonate adduct with triphenyl-phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon-ate -SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra-hedral coordination. In the crystal, adjacent binuclear mol-ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis ...[more]

PMID: 21587763

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