Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Chlorido[hydridotris(pyrazol-1-yl-?N)borato](1H-pyrazole-?N)(triphenyl-phosphine-?P)ruthenium(II).

ABSTRACT: In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N',N''-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol-ecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN(4) octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547?(10):0.453?(10) ratio, and a weak intra-molecular N-H?Cl hydrogen bond generates an S(5) ring.

SUBMITTER: Huang CC

PROVIDER: S-EPMC3006890 | biostudies-other | 2010

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Chlorido[hydridotris(pyrazol-1-yl-κN)borato](1H-pyrazole-κN)(triphenyl-phosphine-κP)ruthenium(II).

Huang Chiung-Cheng CC Chen Han-Gung HG Lo Yih Hsing YH Hsu Li-Sheng LS Lin Chia-Her CH

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N',N''-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol-ecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN(4) octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ra ...[more]

PMID: 21587719

Similar Datasets

(Benzonitrile-?N)chlorido[hydrido-tris(pyrazol-1-yl-?N)borato](triphenyl-phosphine-?P)ruthenium(II) ethanol solvate.

Project description:The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo-nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa-hedron with an average N-Ru-N bite angle of the Tp ligand of 86.6?(2)°.

| S-EPMC2968787 | biostudies-literature

(Dithio-benzoato-κS,S')[hydridotris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II).

Project description:Reaction of [Ru(Tp)Cl(PPh(3))(2)] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(C(7)H(5)S(2))(C(18)H(15)P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru-S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N-Ru-N angle is 86.31°.

| S-EPMC2960112 | biostudies-literature

(Ammine)(carbon-yl)[hydridotris(pyrazol-1-yl-?N(2))borato](triphenyl-phosphine-?P)ruthenium(II) chloride dichloro-methane disolvate.

Project description:In the title compound, [Ru(CO)(NH(3))(C(9)H(10)BN(6))(C(18)H(15)P)]Cl·2CH(2)Cl(2), the coordination environment around the Ru(II) atom is distorted octa-hedral. One of the Ru-N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N-H?Cl hydrogen bonds link the complex cations and Cl(-) anions. ?-? inter-actions between the pyrazole rings [centroid-centroid distance = 3.764?(3)?Å] are also present.

| S-EPMC3515116 | biostudies-literature

(Benzophenone imine-κN)-chlorido(hydrido-tripyrazolyl-borato)-(triphenyl-phosphine)ruthenium(II) diethyl ether solvate.

Project description:The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is [(CH)(3)N(2)](3)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octa-hedron and the bite angle of the Tp ligand produces an average N-Ru-N angle of 86.3 (9)°. The three Ru-N(Tp) bond lengths [2.117 (2), 2.079 (2) and 2.084 (2) Å] are slightly longer than the average distance (2.038 Å) in other ruthenium-Tp complexes.

| S-EPMC2959639 | biostudies-literature

Azido-(benzonitrile-?N)[hydrido-tris(pyrazol-1-yl-?N)borato](triphenyl-phosphine-?P)ruthenium(II).

Project description:Facile ligand substitution is observed when the ruthenium-azide complex, [RuN(3)(Tp)(PPh(3))(2)] [Tp,HB(pz)(3), pz = pyrazol-yl, PPh(3) = triphenyl-phosphine] is treated with benzo-nitrile, yielding the title compound, [Ru(C(9)H(10)BN(6))(N(3))(C(7)H(5)N)(C(18)H(15)P)]. The asymmetric unit contains two crystallographically independent mol-ecules. In each one, the Ru(II) atom is six-coordinated in a distorted octa-hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl-phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru-N-N angle of 124.9?(3)°.

| S-EPMC3006820 | biostudies-other

3-Chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid-triphenyl-phosphine oxide (1/1).

Project description:In the title 1:1 adduct, C(11)H(10)ClN(3)O(2)·C(18)H(15)OP, the dihedral angle between the pyridine and pyrazole rings is 10.3 (2)°. The two components of the adduct are linked by an O-H⋯O hydrogen bond.

| S-EPMC2962060 | biostudies-literature

Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol-yl)methanone]palladium(II).

Project description:In the title compound, [PdCl(2)(C(5)H(8)N(2))(C(12)H(12)N(2)O)], the Pd atom adopts a slightly distorted trans-PdCl(2)N(2) square-planar arrangement. The different Pd-N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N-H⋯Cl linkages.

| S-EPMC2915136 | biostudies-literature

trans-(4-Acetyl-naphth-yl)chlorido-bis(triphenyl-phosphine-?P)nickel(II) dichloro-methane solvate.

Project description:The title compound, [Ni(C(12)H(9)O)Cl(C(18)H(15)P)(2)]·CH(2)Cl(2), was synthesized from the reaction between 1-acetyl-4-chloro-naphthalene, NiCl(2)·6H(2)O and triphenyl-phosphine (PPh(3)) in ethanol. The compound contains one crystallographically unique nickel ion in a pseudo-square-planar geometry.

| S-EPMC2959258 | biostudies-literature

(?-Cyclo-penta-dien-yl)(propionitrile-?N)bis-(triphenyl-phosphine-?P)ruthenium(II) trifluoro-methane-sulfonate.

Project description:The title compound, [Ru(C(5)H(5))(C(3)H(5)N)(C(18)H(15)P)(2)]CF(3)SO(3), forms yellow crystals with a distinctly hemimorphic habit. It contains a half-sandwich complex of ruthenium with a three-legged piano-stool geometry, with Ru-P = 2.3585?(4) and 2.3312?(4)?Å, and Ru-N = 2.0422?(15)?Å?as the legs. The CF(3)SO(3) (-) anion is anchored in the crystal lattice by C-H?O and C-H?F hydrogen bonds, with C?F,O distances starting at 3.125?(2)?Å.

| S-EPMC2971339 | biostudies-literature

catena-Poly[[[aqua-copper(II)]bis-[?-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis-(tetra-fluorido-borate) bis-(triphenyl-phosphine oxide) monohydrate].

Project description:The title compound, {[Cu(C(10)H(14)N(4)Se)(2)(H(2)O)](BF(4))(2)·2C(18)H(15)PO·H(2)O}(n), has a polymeric structure where each Cu(II) ion adopts a square-pyramidal coordination constituted by four N atoms of pyrazole moieties in the equatorial plane and an axial O atom of a water mol-ecule. A pair of bis-(3,5-dimethyl-1H-pyrazol-4-yl) selenide ligands bridges the Cu(II) centres into a chain extending along the c axis. The water mol-ecules, anions and triphenyl-phosphine oxide mol-ecules are involved in inter-molecular hydrogen bonding, which links the chains into a three-dimensional network.

| S-EPMC2979014 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data