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N-(4,5-Diaza-9H-fluoren-9-yl-idene)-4-meth-oxy-aniline.


ABSTRACT: In the title compound, C(18)H(13)N(3)O, the diaza-fluorene ring system is almost coplanar (r.m.s. deviation = 0.0640?Å) and subtends an angle of 61.5?(4)° with the plane of the meth-oxy-substituted benzene ring. In the crystal structure, pairs of C-H?O hydrogen bonds link mol-ecules into centrosymmetric dimers parallel to the ab plane. Mol-ecules are also stacked in an obverse fashion along the c axis by a variety of ?-? inter-actions with centroid-centroid distances in the range 3.557?(2)-3.921?(2)?Å.

SUBMITTER: Cang H 

PROVIDER: S-EPMC3006891 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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N-(4,5-Diaza-9H-fluoren-9-yl-idene)-4-meth-oxy-aniline.

Cang Hui H   Bian Jin-Fa JF   Wang Si-Qing SQ   Wang Jin-Tang JT  

Acta crystallographica. Section E, Structure reports online 20100626 Pt 7


In the title compound, C(18)H(13)N(3)O, the diaza-fluorene ring system is almost coplanar (r.m.s. deviation = 0.0640 Å) and subtends an angle of 61.5 (4)° with the plane of the meth-oxy-substituted benzene ring. In the crystal structure, pairs of C-H⋯O hydrogen bonds link mol-ecules into centrosymmetric dimers parallel to the ab plane. Mol-ecules are also stacked in an obverse fashion along the c axis by a variety of π-π inter-actions with centroid-centroid distances in the range 3.557 (2)-3.921  ...[more]

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