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Trans-Dichlorido(2,2-dimethyl-propane-1,3-diamine)-bis-(triphenyl-phosphane)ruthenium(II).

ABSTRACT: In the title compound, [RuCl(2)(C(5)H(14)N(2))(C(18)H(15)P)(2)], the Ru(II) atom is six-coordinated, forming a slightly distorted octa-hedral geometry, with two chloride ions in an axial arrangement, and two P atoms of two triphenyl-phosphane and two chelating N atoms of the bidentate 2,2-dimethyl-propane-1,3-diamine ligand located in the equatorial plane. The average Ru-P, Ru-N and Ru-Cl bond lengths are 2.325?(18), 2.1845?(7) and 2.4123?(12)?Å, respectively.

SUBMITTER: Khanfar MA

PROVIDER: S-EPMC3006909 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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trans-Dichlorido(2,2-dimethyl-propane-1,3-diamine)-bis-(triphenyl-phosphane)ruthenium(II).

Khanfar Monther A MA Warad Ismail I Aldamen Murad A MA

Acta crystallographica. Section E, Structure reports online 20100605 Pt 7

In the title compound, [RuCl(2)(C(5)H(14)N(2))(C(18)H(15)P)(2)], the Ru(II) atom is six-coordinated, forming a slightly distorted octa-hedral geometry, with two chloride ions in an axial arrangement, and two P atoms of two triphenyl-phosphane and two chelating N atoms of the bidentate 2,2-dimethyl-propane-1,3-diamine ligand located in the equatorial plane. The average Ru-P, Ru-N and Ru-Cl bond lengths are 2.325 (18), 2.1845 (7) and 2.4123 (12) Å, respectively. ...[more]

PMID: 21587674

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