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16-[(E)-Benzyl-idene]-2-hy-droxy-12,13-diphenyl-1,11-diaza-penta-cyclo-[12.3.1.0.0.0]octa-deca-3(8),4,6-triene-9,15-dione.

ABSTRACT: In the title compound, C(35)H(28)N(2)O(3), an intra-molecular O-H?N hydrogen bonds generates a five-membered ring, producing an S(5) ring motif. The piperidone ring adopts a half-chair conformation and the two pyrrolidine rings adopt an envelope conformation. The dihedral angles formed between adjacent benzene rings are 74.39?(5) and 37.70?(6)°. In the crystal crystal, inter-molecular C-H?O hydrogen bonds link mol-ecules into dimers, which are further inter-connected into two-dimensional networks parallel to the ac plane by inter-molecular C-H?O hydrogen bonds. The crystal structure is consolidated by weak C-H?? inter-actions.

SUBMITTER: Kumar RS

PROVIDER: S-EPMC3007256 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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16-[(E)-Benzyl-idene]-2-hy-droxy-12,13-diphenyl-1,11-diaza-penta-cyclo-[12.3.1.0.0.0]octa-deca-3(8),4,6-triene-9,15-dione.

Kumar Raju Suresh RS Osman Hasnah H Ali Mohamed Ashraf MA Goh Jia Hao JH Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

In the title compound, C(35)H(28)N(2)O(3), an intra-molecular O-H⋯N hydrogen bonds generates a five-membered ring, producing an S(5) ring motif. The piperidone ring adopts a half-chair conformation and the two pyrrolidine rings adopt an envelope conformation. The dihedral angles formed between adjacent benzene rings are 74.39 (5) and 37.70 (6)°. In the crystal crystal, inter-molecular C-H⋯O hydrogen bonds link mol-ecules into dimers, which are further inter-connected into two-dimensional network ...[more]

PMID: 21588383

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