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Poly[bis-[?-1,4-bis-(1,2,4-triazol-1-ylmeth-yl)benzene-?N:N]dichloridomanganese(II)].

ABSTRACT: The Mn(II) atom in the title coordination polymer, [MnCl(2)(C(12)H(12)N(6))(2)](n), lies on a center of inversion in a six-coordinate octa-hedral environment comprising four N-atom donors from four N-heterocyclic ligands and two chloride atoms. Bridging by the ligands results in a layer structure of a 14.79?(5) × 14.79?(5)?Å (4,4) rhombic net topology, with the Mn(II) atoms all lying on a plane. The parallel layers stack in an ABCABC… manner through inter-layer C-H?N and C-H?Cl hydrogen bonds.

SUBMITTER: Ding B

PROVIDER: S-EPMC3007432 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Poly[bis-[μ-1,4-bis-(1,2,4-triazol-1-ylmeth-yl)benzene-κN:N]dichloridomanganese(II)].

Ding Bin B Zou Hong-Ai HA

Acta crystallographica. Section E, Structure reports online 20100714 Pt 8

The Mn(II) atom in the title coordination polymer, [MnCl(2)(C(12)H(12)N(6))(2)](n), lies on a center of inversion in a six-coordinate octa-hedral environment comprising four N-atom donors from four N-heterocyclic ligands and two chloride atoms. Bridging by the ligands results in a layer structure of a 14.79 (5) × 14.79 (5) Å (4,4) rhombic net topology, with the Mn(II) atoms all lying on a plane. The parallel layers stack in an ABCABC… manner through inter-layer C-H⋯N and C-H⋯Cl hydrogen bonds. ...[more]

PMID: 21588164

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