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Di-?-sulfato-?O:O'-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate.

ABSTRACT: In the title centrosymmetric dinuclear compound, [Mn(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Mn(II) atom is octa-hedrally coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (ip) ligand, two O atoms belonging to two bridging sulfate anions and two water O atoms. In the crystal structure, the complex mol-ecules and the uncoodinated water mol-ecules are connected by O-H?O, O-H?N and N-H?O hydrogen bonds into a three-dimensional network. A ?-? stacking inter-action between the pyridyl ring of the ip ligand and the benzene ring of the neighboring ligand [centroid-centroid distance = 3.579?(2)?Å] is also observed.

SUBMITTER: Yang MX

PROVIDER: S-EPMC3007874 | biostudies-other | 2010 Aug

REPOSITORIES: biostudies-other

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Di-μ-sulfato-κO:O'-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate.

Yang Ming-Xing MX Lin Shen S Chen Li-Juan LJ Chen Xiao-Hua XH

Acta crystallographica. Section E, Structure reports online 20100818 Pt 9

In the title centrosymmetric dinuclear compound, [Mn(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Mn(II) atom is octa-hedrally coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (ip) ligand, two O atoms belonging to two bridging sulfate anions and two water O atoms. In the crystal structure, the complex mol-ecules and the uncoodinated water mol-ecules are connected by O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds into a three-dimensional network. A π-π stacking inter-action ...[more]

PMID: 21588521

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