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A one-dimensional inorganic-organic hybrid compound: catena-poly[ethyl-enediammonium [indate(III)-di-?-hydrogenphosphato(V)-?-hydroxido] monohydrate].

ABSTRACT: The title compound, (C(2)H(10)N(2))[In(HPO(4))(2)(OH)]·H(2)O, was synthesized under hydro-thermal conditions. The structure of this hybrid compound consists of isolated inorganic chains with composition (?)[In(HPO(4))(4/2)(OH)(2/2)] running along [010]. The coordination of the In(III) atom is distorted octa-hedral. The ethyl-enediammonium cation and the disordered water mol-ecule (site-occupation factors = 0.7:0.3) ensure the cohesion of the structure via N-H?O and O-H?O hydrogen bonds.

SUBMITTER: Assani A 

PROVIDER: S-EPMC3007876 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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A one-dimensional inorganic-organic hybrid compound: catena-poly[ethyl-enediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate].

Assani Abderrazzak A   Saadi Mohamed M   El Ammari Lahcen L  

Acta crystallographica. Section E, Structure reports online 20100828 Pt 9

The title compound, (C(2)H(10)N(2))[In(HPO(4))(2)(OH)]·H(2)O, was synthesized under hydro-thermal conditions. The structure of this hybrid compound consists of isolated inorganic chains with composition (∞)[In(HPO(4))(4/2)(OH)(2/2)] running along [010]. The coordination of the In(III) atom is distorted octa-hedral. The ethyl-enediammonium cation and the disordered water mol-ecule (site-occupation factors = 0.7:0.3) ensure the cohesion of the structure via N-H⋯O and O-H⋯O hydrogen bonds. ...[more]