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Trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane}palladium(II).

ABSTRACT: The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3550?(7) and 2.2906?(7)?Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two ?-stacked rings of 3.505?(3)?Å. Intra- and intermolecular C-H?Cl hydrogen bonds also occur.

SUBMITTER: Muller A

PROVIDER: S-EPMC3009084 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane}palladium(II).

Muller Alfred A Meijboom Reinout R

Acta crystallographica. Section E, Structure reports online 20101023 Pt 11

The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) Å. Intra- and intermolecular C-H⋯Cl hydrogen bonds also occur. ...[more]

PMID: 21588880

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