Unknown

Dataset Information

0

1-Methane-sulfonyl-1H-1,2,3-benzotriazole.

ABSTRACT: The mol-ecular geometry of the title compound, C(7)H(7)N(3)O(2)S, does not differ much from that of the previously reported 4-toluene-sulfonyl analogue. Unlike the latter compound, however, mol-ecules of the title compound associate primarily via ?-? stacking inter-actions of their benzene rings [centroid-centroid distance = 3.5865?(8)?Å], forming columnar stacks along the crystallographic 2(1) axes. These stacks are inter-connected via weak C-H?O and C-H?N hydrogen bonds.

SUBMITTER: Stepnicka P 

PROVIDER: S-EPMC3009158 | biostudies-other | 2010

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

1-Methane-sulfonyl-1H-1,2,3-benzotriazole.

Stěpnička Petr P   Solařová Hana H   Císařová Ivana I  

Acta crystallographica. Section E, Structure reports online 20101020 Pt 11

The mol-ecular geometry of the title compound, C(7)H(7)N(3)O(2)S, does not differ much from that of the previously reported 4-toluene-sulfonyl analogue. Unlike the latter compound, however, mol-ecules of the title compound associate primarily via π-π stacking inter-actions of their benzene rings [centroid-centroid distance = 3.5865 (8) Å], forming columnar stacks along the crystallographic 2(1) axes. These stacks are inter-connected via weak C-H⋯O and C-H⋯N hydrogen bonds. ...[more]

Similar Datasets

Unknown 1-Chloro-1H-1,2,3-benzotriazole.
| S-EPMC3589014 | biostudies-literature
Unknown 1-Chloro-methyl-1H-1,2,3-benzotriazole.
| S-EPMC3011609 | biostudies-literature
Unknown 1-[2-(1H-Benzimidazol-2-yl)eth-yl]-1H-1,2,3-benzotriazole.
| S-EPMC3238838 | biostudies-other
Unknown Photocatalytic Transformations of 1H-Benzotriazole and Benzotriazole Derivates.
| S-EPMC7560172 | biostudies-literature
Unknown 1-Benzyl-1H-benzotriazole 3-oxide-1-hy-droxy-1H-benzotriazole (1/1).
| S-EPMC3414323 | biostudies-literature
Unknown 1-Benzyl-1H-benzotriazole.
| S-EPMC3344078 | biostudies-literature
Unknown Bis{1-[(benzo-yloxy)meth-yl]-1H-1,2,3-benzotriazole-?N(3)}(nitrato-?(2)O,O')-silver(I).
| S-EPMC3343790 | biostudies-literature
Unknown 1-Benz-yloxy-1H-benzotriazole.
| S-EPMC3394030 | biostudies-literature
Unknown Efficient synthesis of 1-sulfonyl-1,2,3-triazoles.
| S-EPMC2982995 | biostudies-literature
Unknown Transannulation of 1-sulfonyl-1,2,3-triazoles with heterocumulenes.
| S-EPMC3645925 | biostudies-literature