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Trans-Bromido(pyrimidinyl-?C)bis-(triphenyl-phosphane-?P)palladium(II).

ABSTRACT: In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd(II) atom is distorted square-planar with the Pd(II) atom displaced by 0.0150?(5)?Å from the least-squares BrP(2)C plane. Two PPh(3) ligands are in trans positions [P-Pd-P = 176.743?(17)°], while the pyrimidinyl ligand and Br atom are trans to one another [C-Pd-Br = 176.56?(5)°]. Structural parameters from NMR, IR and mass spectra are in agreement with the crystal structure of the title compound.

SUBMITTER: Lee GH

PROVIDER: S-EPMC3009198 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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trans-Bromido(pyrimidinyl-κC)bis-(triphenyl-phosphane-κP)palladium(II).

Lee Gene-Hsiang GH Wang Hsiao-Fen HF Yih Kuang-Hway KH

Acta crystallographica. Section E, Structure reports online 20101002 Pt 11

In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd(II) atom is distorted square-planar with the Pd(II) atom displaced by 0.0150 (5) Å from the least-squares BrP(2)C plane. Two PPh(3) ligands are in trans positions [P-Pd-P = 176.743 (17)°], while the pyrimidinyl ligand and Br atom are trans to one another [C-Pd-Br = 176.56 (5)°]. Structural parameters from NMR, IR and mass spectra are in agreement with the crystal structure of the title compound. ...[more]

PMID: 21588792

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trans-Bromido(pyrimidinyl-?C)bis-(triphenyl-phosphane-?P)palladium(II).

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