Unknown

Dataset Information

0

Bis({tris[2-(3,5-di-tert-butyl-2-oxido-benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate.

ABSTRACT: The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N',N''-tris-(3,5-di-tert-butyl-salicyl-ide-natoamino)-triethyl-amine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce-N(imine) distance of 2.860?(2)?Å and an average C-N(amine) distance of 2.619?Å within a distorted monocapped octahedral coordination.

SUBMITTER: Drose P 

PROVIDER: S-EPMC3009372 | biostudies-other | 2010

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Bis({tris[2-(3,5-di-tert-butyl-2-oxido-benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate.

Dröse Peter P   Hrib Cristian G CG   Edelmann Frank T FT  

Acta crystallographica. Section E, Structure reports online 20101013 Pt 11

The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N',N''-tris-(3,5-di-tert-butyl-salicyl-ide-natoamino)-triethyl-amine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce-N(imine) distance of 2.860 (2) Å and an average C-N(amine) distance of 2.619 Å within a distorted monocapped octahedral coordination. ...[more]

Similar Datasets

Unknown Tris(4,4'-di-tert-butyl-2,2'-bipyridine-?N,N')molybdenum(II) ?(6)-oxido-dodeca-?(2)-oxido-hexa-oxidohexa-molybdate(VI) acetonitrile tetra-solvate.
| S-EPMC3238728 | biostudies-literature
Unknown (3,5-Di-tert-butyl-2-eth-oxy-benzyl-idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth-yl]amine.
| S-EPMC3414966 | biostudies-literature
Unknown Diethyl 2,2-bis-(3,5-di-tert-butyl-4-hy-droxy-benz-yl)malonate.
| S-EPMC3275203 | biostudies-literature
Unknown Bis(tetra-butyl-ammonium) [2-(eth-oxy-carbony)phenyl-imido]-?(6)-oxido-dodeca-?(2)-oxido-penta-oxidohexa-molybdenum diethyl ether hemisolvate.
| S-EPMC3393191 | biostudies-literature
Unknown Bis[tris(3-tert-butyl-5-methyl-pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate.
| S-EPMC2969540 | biostudies-literature
Unknown Di-?-iodido-bis-[(diethyl ether-?O)(?-1,3-di-tert-butyl-cyclo-penta-dien-yl)ytterbium(II)].
| S-EPMC2915154 | biostudies-literature
Unknown Tris(tert-butyl isocyanide-κC)carbonylnickel(0).
| S-EPMC2961925 | biostudies-literature
Unknown Tris(4-tert-butyl-phen-yl)phosphine oxide.
| S-EPMC2980249 | biostudies-literature
Unknown Tris(2,4-di-tert-butyl-phen-yl) phosphate.
| S-EPMC3008051 | biostudies-literature
Unknown N'-(3,5-Di-tert-butyl-4-hydroxy-benzyl-idene)-2-hydroxy-benzohydrazide methanol solvate.
| S-EPMC2962083 | biostudies-other