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Chlorido(4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine)-platinum(II) chloride toluene monosolvate.

ABSTRACT: In the title compound, [PtCl(C(27)H(35)N(3))]Cl·C(7)H(8), the Pt(II) atom is coordinated in a pseudo-square-planar fashion by the N atoms of a 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine (tbtrpy) ligand and a Cl atom. The Pt-N distance of the N atom on the central pyridine is 1.941?(4)?Å, while the peripheral N atoms have Pt-N distances of 2.015?(4) and 2.013?(4)?Å. The Pt-Cl bond distance is 2.3070?(10)?Å. The cations pack as dimers in a head-to-tail orientation with an inter-molecular Pt?Pt distance of 3.2774?(3)?Å and Pt?N distances of 3.599?(4), 3.791?(4) and 4.115?(4)?Å. The solvent mol-ecule is disordered and occupies two positions with a ratio of 0.553?(6):0.447?(6).

SUBMITTER: Batrice RJ

PROVIDER: S-EPMC3011477 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Chlorido(4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine)-platinum(II) chloride toluene monosolvate.

Batrice Rami J RJ Nesterov Vladimir N VN Smucker Bradley W BW

Acta crystallographica. Section E, Structure reports online 20101130 Pt 12

In the title compound, [PtCl(C(27)H(35)N(3))]Cl·C(7)H(8), the Pt(II) atom is coordinated in a pseudo-square-planar fashion by the N atoms of a 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine (tbtrpy) ligand and a Cl atom. The Pt-N distance of the N atom on the central pyridine is 1.941 (4) Å, while the peripheral N atoms have Pt-N distances of 2.015 (4) and 2.013 (4) Å. The Pt-Cl bond distance is 2.3070 (10) Å. The cations pack as dimers in a head-to-tail orientation with an inter-molecular Pt⋯P ...[more]

PMID: 21589354

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