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2,4-Dichloro-N-(1,3-thia-zol-2-yl)benzamide.

ABSTRACT: In the mol-ecular structure of the title compound, C(10)H(6)Cl(2)N(2)OS, the dihedral angle between the benzene plane and the plane defined by the amide functionality is 8.6?(1)°, while the thia-zole ring plane is twisted with respect to the amide plane by 68.71?(5)°. In the crystal, pairs of inter-molecular N-H?N hydrogen-bond inter-actions connect the mol-ecules into inversion dimers. ?-? inter-actions are also observed between neighbouring thia-zole and phen-yl rings [centroid-centroid distance = 3.5905?(13)?Å] and a weak C-H?? interaction also occurs.

SUBMITTER: Saeed S

PROVIDER: S-EPMC3011524 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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2,4-Dichloro-N-(1,3-thia-zol-2-yl)benzamide.

Saeed Sohail S Rashid Naghmana N Wong Wing-Tak WT

Acta crystallographica. Section E, Structure reports online 20101106 Pt 12

In the mol-ecular structure of the title compound, C(10)H(6)Cl(2)N(2)OS, the dihedral angle between the benzene plane and the plane defined by the amide functionality is 8.6 (1)°, while the thia-zole ring plane is twisted with respect to the amide plane by 68.71 (5)°. In the crystal, pairs of inter-molecular N-H⋯N hydrogen-bond inter-actions connect the mol-ecules into inversion dimers. π-π inter-actions are also observed between neighbouring thia-zole and phen-yl rings [centroid-centroid distan ...[more]

PMID: 21589387

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