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1,2-Bis(dimethyl-amino)-1,2-bis-(2,4,6-triisopropyl-phen-yl)diborane(4).

ABSTRACT: In the mol-ecular structure of the title compound, C(34)H(58)B(2)N(2), each B atom of the diborane(4) is connected to one dimethyl-amino group and one Tip ligand (Tip = 2,4,6-triisopropyl-phen-yl). These findings indicate that the increased steric demand of the Tip groups exerts influence solely on the B-B separation but not on the overall geometry of the title compound.

SUBMITTER: Braunschweig H 

PROVIDER: S-EPMC3011803 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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1,2-Bis(dimethyl-amino)-1,2-bis-(2,4,6-triisopropyl-phen-yl)diborane(4).

Braunschweig Holger H   Damme Alexander A  

Acta crystallographica. Section E, Structure reports online 20101130 Pt 12

In the mol-ecular structure of the title compound, C(34)H(58)B(2)N(2), each B atom of the diborane(4) is connected to one dimethyl-amino group and one Tip ligand (Tip = 2,4,6-triisopropyl-phen-yl). These findings indicate that the increased steric demand of the Tip groups exerts influence solely on the B-B separation but not on the overall geometry of the title compound. ...[more]