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(E)-2-[1-(3-Chloro-4-fluoro-phen-yl)ethyl-idene]hydrazinecarbothio-amide.

ABSTRACT: In the crystal of the title compound, C(9)H(9)ClFN(3)S, the molecules are inter-connected by N-H?S and N-H?F hydrogen bonds. There are two different N-H?S hydrogen bond: the stronger one links mol-ecules into infinite chains along the b axis with graph-set motif C(4), while the weaker N-H?S hydrogen bond combines with the previous one into an R(2) (2)(8) network. Moreover, the chains are linked into layers parallel to (102) by weak N-H?F hydrogen bonds, which form an R(2) (2)(22) ring motif. In addition, there are also weak ?-? inter-actions between the benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.8997?(15)?Å].

SUBMITTER: Zhai XR

PROVIDER: S-EPMC3050128 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(E)-2-[1-(3-Chloro-4-fluoro-phen-yl)ethyl-idene]hydrazinecarbothio-amide.

Zhai Xiu-Rong XR

Acta crystallographica. Section E, Structure reports online 20101211 Pt 1

In the crystal of the title compound, C(9)H(9)ClFN(3)S, the molecules are inter-connected by N-H⋯S and N-H⋯F hydrogen bonds. There are two different N-H⋯S hydrogen bond: the stronger one links mol-ecules into infinite chains along the b axis with graph-set motif C(4), while the weaker N-H⋯S hydrogen bond combines with the previous one into an R(2) (2)(8) network. Moreover, the chains are linked into layers parallel to (102) by weak N-H⋯F hydrogen bonds, which form an R(2) (2)(22) ring motif. In ...[more]

PMID: 21522787

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