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(4-Nitro-phenolato)(subphthalo-cyaninato)boron(III).

ABSTRACT: The main feature of the structure of the title compound, C(30)H(16)BN(7)O(3) or NO(2)PhO-BsubPc, are pairs of mol-ecules linked through ?-inter-actions between the concave faces of the BsubPc fragments at a distance of 3.5430?(11)?Å across an inversion centre. However, the angle between the planes of the five- and six-menbered rings involved in this inter-action is 1.44?(10)°, causing the inter-acting BsubPcs units to be slightly askew rather than parallel as is typical for ?-stacking inter-actions.

SUBMITTER: Paton AS

PROVIDER: S-EPMC3050212 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(4-Nitro-phenolato)(subphthalo-cyaninato)boron(III).

Paton Andrew S AS Lough Alan J AJ Bender Timothy P TP

Acta crystallographica. Section E, Structure reports online 20101208 Pt 1

The main feature of the structure of the title compound, C(30)H(16)BN(7)O(3) or NO(2)PhO-BsubPc, are pairs of mol-ecules linked through π-inter-actions between the concave faces of the BsubPc fragments at a distance of 3.5430 (11) Å across an inversion centre. However, the angle between the planes of the five- and six-menbered rings involved in this inter-action is 1.44 (10)°, causing the inter-acting BsubPcs units to be slightly askew rather than parallel as is typical for π-stacking inter-acti ...[more]

PMID: 21522767

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