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[N-Benzyl-N-(diphenyl-phosphanylmeth-yl)pyridin-2-amine]-chloridomethyl-platinum(II).

ABSTRACT: In the mononuclear title complex, [Pt(CH(3))Cl(C(25)H(23)N(2)P)], the N-benzyl-N-(diphenyl-phosphanylmeth-yl)pyridin-2-amine functions as a bidentate ligand with the pyridyl N atom and the phosphine P atom chelating the Pt(II) ion, forming a six-membered metallocycle. The Pt(II) atom adopts a square-planar coordination geometry with one methyl group and one chloride ligand bonding to the metal center in a cis relationship. C-H?? and C-H?Cl inter-actions help to consolidate the packing.

SUBMITTER: Wang ZW

PROVIDER: S-EPMC3050312 | biostudies-other | 2010 Dec

REPOSITORIES: biostudies-other

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[N-Benzyl-N-(diphenyl-phosphanylmeth-yl)pyridin-2-amine]-chloridomethyl-platinum(II).

Wang Zhi-Wei ZW Qiao Peng P Wang Zi-Jia ZJ Wan Chong-Qing CQ

Acta crystallographica. Section E, Structure reports online 20101204 Pt 1

In the mononuclear title complex, [Pt(CH(3))Cl(C(25)H(23)N(2)P)], the N-benzyl-N-(diphenyl-phosphanylmeth-yl)pyridin-2-amine functions as a bidentate ligand with the pyridyl N atom and the phosphine P atom chelating the Pt(II) ion, forming a six-membered metallocycle. The Pt(II) atom adopts a square-planar coordination geometry with one methyl group and one chloride ligand bonding to the metal center in a cis relationship. C-H⋯π and C-H⋯Cl inter-actions help to consolidate the packing. ...[more]

PMID: 21522558

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