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(2,2'-Bipyridine-?N,N')bromido(1,4,7-trithia-cyclo-nonane-?S,S',S'')ruthenium(II) hexa-fluoridophosphate.

ABSTRACT: The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithia-cyclo-nonane and bpy is 2,2'-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with only the chloride ligand being substituted by a bromide ligand. The presence of a PF(6) (-) anion (alongside with the coordinated bromide ligand) promotes the existence of an extensive network of weak C-H?X (X = F, Br) inter-actions.

SUBMITTER: Fernandes JA

PROVIDER: S-EPMC3051521 | biostudies-other | 2011

REPOSITORIES: biostudies-other

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(2,2'-Bipyridine-κN,N')bromido(1,4,7-trithia-cyclo-nonane-κS,S',S'')ruthenium(II) hexa-fluoridophosphate.

Fernandes José A JA Almeida Paz Filipe A FA Ramos Ana I AI Santos Teresa M TM Braga Susana S SS

Acta crystallographica. Section E, Structure reports online 20110126 Pt 2

The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithia-cyclo-nonane and bpy is 2,2'-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with only the chloride ligand being substituted by a bromide ligand. The presence of a PF(6) (-) anion (alongside with the coordinated bromide ligand) promotes the existence of an extensive network of weak ...[more]

PMID: 21522914

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