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Bis(2-amino-1,3-thia-zole-?N)diazido-zinc.

ABSTRACT: In the title complex, [Zn(N(3))(2)(C(3)H(4)N(2)S)(2)], the Zn(II) atom is tetra-hedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-amino-thia-zole ligands. Intra-molecular N-H?N hydrogen bonds between the amino groups of both 2-amino-thia-zole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Inter-molecular N-H?N hydrogen bonds link the mol-ecules into zigzag sheets in the ac plane.

SUBMITTER: Suh SW

PROVIDER: S-EPMC3051526 | biostudies-other | 2011 Jan

REPOSITORIES: biostudies-other

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Bis(2-amino-1,3-thia-zole-κN)diazido-zinc.

Suh Seung Wook SW Kim Chong-Hyeak CH Kim Inn Hoe IH

Acta crystallographica. Section E, Structure reports online 20110108 Pt 2

In the title complex, [Zn(N(3))(2)(C(3)H(4)N(2)S)(2)], the Zn(II) atom is tetra-hedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-amino-thia-zole ligands. Intra-molecular N-H⋯N hydrogen bonds between the amino groups of both 2-amino-thia-zole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Inter-molecular N-H⋯N hydrogen bonds link the mol-ecules into zigzag sheets in the ac plane ...[more]

PMID: 21522822

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