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2-{2-[(2,6-Dichloro-phen-yl)amino]-phen-yl}ethanol.

ABSTRACT: In the title compound, C(14)H(13)Cl(2)NO, the 2,6-dichloro-anilino unit is roughly planar (r.m.s. deviation = 0.0298?Å) and makes a dihedral angle of 67.71?(4)° with the benzene ring containing the ethanol group. The C-C-O fragment is oriented at a dihedral angle of 64.94?(9)° with respect to its parent benzene ring. The molecular conformation is stabilised by a bifurcated N-H?(O,Cl) hydrogen bond. C-H??, O-H?? and ?-? inter-actions [centroid-centroid distance = 3.5706?(11)?Å] stabilize the crystal structure.

SUBMITTER: Nasirullah

PROVIDER: S-EPMC3051747 | biostudies-other | 2011

REPOSITORIES: biostudies-other

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2-{2-[(2,6-Dichloro-phen-yl)amino]-phen-yl}ethanol.

Nasirullah Ul Islam Nazar N Tahir M Nawaz MN Khan Ikhtiar I

Acta crystallographica. Section E, Structure reports online 20110108 Pt 2

In the title compound, C(14)H(13)Cl(2)NO, the 2,6-dichloro-anilino unit is roughly planar (r.m.s. deviation = 0.0298 Å) and makes a dihedral angle of 67.71 (4)° with the benzene ring containing the ethanol group. The C-C-O fragment is oriented at a dihedral angle of 64.94 (9)° with respect to its parent benzene ring. The molecular conformation is stabilised by a bifurcated N-H⋯(O,Cl) hydrogen bond. C-H⋯π, O-H⋯π and π-π inter-actions [centroid-centroid distance = 3.5706 (11) Å] stabilize the crys ...[more]

PMID: 21522965

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