Ontology highlight
ABSTRACT:
SUBMITTER: Shawkataly OB
PROVIDER: S-EPMC3051758 | biostudies-other | 2011
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20110115 Pt 2
In the title triangulo-triruthenium compound, [Ru(3)(C(36)H(27)As)(C(25)H(22)P(2))(CO)(9)], the bis-(diphenyl-phosphan-yl)methane ligand bridges an Ru-Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. In each biphenyl unit, the phenyl rings are twisted from each other, making dihedral angles of 51.22 ...[more]