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Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]isopropyl-amine-?N,P}palladium(II) dimethyl sulfoxide monosolvate.

ABSTRACT: In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(-) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081?(3)?Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol-ecules form centrosymmetric dimers due to an inter-molecular C-H?O inter-action. The crystal structure is further stabilized through two inter-molecular C-H?? inter-actions.

SUBMITTER: Chiririwa H

PROVIDER: S-EPMC3089087 | biostudies-other | 2011 May

REPOSITORIES: biostudies-other

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Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]isopropyl-amine-κN,P}palladium(II) dimethyl sulfoxide monosolvate.

Chiririwa Haleden H Meijboom Reinout R Omondi Bernard B

Acta crystallographica. Section E, Structure reports online 20110416 Pt 5

In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(-) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol-ecules form centrosymmetric dimers due to an inter-molecular C-H⋯O inter-action. The crystal structure is further stabilized ...[more]

PMID: 21754326

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