Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]isopropyl-amine-?N,P}palladium(II) dimethyl sulfoxide monosolvate.

ABSTRACT: In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(-) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081?(3)?Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol-ecules form centrosymmetric dimers due to an inter-molecular C-H?O inter-action. The crystal structure is further stabilized through two inter-molecular C-H?? inter-actions.

SUBMITTER: Chiririwa H

PROVIDER: S-EPMC3089087 | biostudies-other | 2011 May

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]isopropyl-amine-κN,P}palladium(II) dimethyl sulfoxide monosolvate.

Chiririwa Haleden H Meijboom Reinout R Omondi Bernard B

Acta crystallographica. Section E, Structure reports online 20110416 Pt 5

In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(-) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol-ecules form centrosymmetric dimers due to an inter-molecular C-H⋯O inter-action. The crystal structure is further stabilized ...[more]

PMID: 21754326

Similar Datasets

(SP-4-2)-Chlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]benzyl-amine-κP,N}(meth-yl)palladium(II).

Project description:In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.

| S-EPMC3246930 | biostudies-literature

Bromido({2-[2-(diphenyl-phosphan-yl)benzyl-idene]hydrazin-1-yl-idene}(4-meth-oxy-anilino)methane-thiol-ato)palladium(II) acetone monosolvate.

Project description:In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053?(4)?Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78?(7), 87.05?(7) and 77.50?(7)° with each other. An intra-molecular C-H?N hydrogen bond forms an S(6) ring motif. In the crystal, the complex mol-ecules form infinite chains along the a-axis direction through C-H?Br inter-actions, and a C-H?O inter-action links the main mol-ecule with the acetone solvent mol-ecule.

| S-EPMC3393237 | biostudies-literature

[N,N-Bis(diphenyl-phosphan-yl)benzyl-amine-κP,P']dichloridonickel(II) dichloro-methane monosolvate.

Project description:In the title solvated complex, [NiCl(2)(C(31)H(27)NP(2))]·CH(2)Cl(2), the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the chelating N,N-bis-(diphenyl-phosphan-yl)benzyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. In the crystal, the components are linked by C-H⋯Cl inter-actions.

| S-EPMC3246988 | biostudies-literature

N,N-Bis(diphenyl-phosphan-yl)benzyl-amine.

Project description:In the title compound, C(31)H(27)NP(2), the diphenyl-phosphanyl groups are staggered relative to the PNP backbone. The N atom is displaced by 0.219 (2) Å from the plane formed by the two P atoms and the methylene C atom. The angles around the N atom are 120.84 (16), 113.29 (16) and 120.57 (12)°, indicating that it exhibits a distorted trigonal-pyramidal geometry. There are no classical inter-molecular inter-actions.

| S-EPMC3051494 | biostudies-literature

rac-Dichlorido(1-{(diphenyl-phosphan-yl)[2-(diphenyl-phosphan-yl)phen-yl]meth-yl}ferrocene-?P,P')palladium(II) dimethyl sulfoxide disolvate.

Project description:The racemic title compound, [FePdCl(2)(C(5)H(5))(C(36)H(29)P(2))]·2(CH(3))(2)SO, features a Pd-chelating 1,3-diphosphine, which is substituted at a P-bearing asymmetric C atom by a ferrocenyl group. The Pd(II) atom is in a distorted quadratic coordination by two P and two Cl atoms with bond lengths of 2.2414?(3) and 2.2438?(3)?Å for Pd-P, and 2.3452?(3) and 2.3565?(3)?Å for Pd-Cl. The conformation of the Pd complex is controlled by an intra-molecular slipped ?-? stacking inter-action between a phenyl and a cyclo-penta-dienyl ring with corresponding C?C distances starting at 3.300?(2)?Å and the distance between ring centroids being 3.674?(2)?Å. The crystal structure is stabilized by C-H?Cl and C-H?O hydrogen bonds. The (CH(3))(2)SO solvent mol-ecules are arranged in layers parallel to (101) and are linked in pairs by C-H?O inter-actions. One (CH(3))(2)SO mol-ecule is orientationally disordered [occupancy ratio 0.8766?(17):0.1234?(17)] with sulfur in two positions at both sides of its C(2)O triangle.

| S-EPMC3201499 | biostudies-other

Chlorido{[(E)-2-(diphenyl-phosphan-yl)benzyl-idene](furan-2-ylmeth-yl)amine-?P}gold(I).

Project description:In the title complex, [AuCl(C24H20NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the 'soft' P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au-P = 2.2321?(13)?Å, Au-Cl = 2.2820?(13)?Å and P-Au-Cl = 176.49?(5)°. The furan ring is disordered over two positions in a 0.51?(2):0.49?(2) ratio.

| S-EPMC3588354 | biostudies-literature

Chlorido[2-({[2-(diphenyl-phosphan-yl)-benzyl-idene]amino}-meth-yl)thio-phene-?N,P]methyl-palladium(II).

Project description:In the title compound, [Pd(CH(3))Cl(C(24)H(20)NPS)], the Pd(II) ion is coordinated in a distorted square-planar environment which includes the P and N atoms of the bis-chelating ligand. The thio-phene ring is rotationally ordered, unlike in the majority of crystal structures containing this group.

| S-EPMC3297280 | biostudies-literature

[1,2-Bis(diphenyl-phosphan-yl)ethane-?(2)P,P']dichloridopalladium(II) dimethyl sulfoxide monosolvate.

Project description:In the title compound, [PdCl(2)(C(26)H(24)P(2))]·C(2)H(6)OS, the Pd(II) atom adopts a distorted cis-PdCl(2)P(2) square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methyl-ene C atom in the flap position. The S and C atoms of the dimethyl sulfoxide (DMSO) solvent mol-ecule are disordered over two sets of sites in a 0.8976?(18):0.1024?(18) ratio. The DMSO O atom accepts three C-H?O hydrogen bonds from an adjacent complex mol-ecule.

| S-EPMC3393233 | biostudies-literature

Chlorido{N-[(E)-2-(diphenyl-phosphan-yl)benzyl-idene]-2-(thio-phen-2-yl)ethan-amine-?P}gold(I).

Project description:The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent mol-ecules in the asymmetric unit in which the thio-phene fragments are disordered over two sets of sites with 0.537?(10):0.463?(10) and 0.701?(9):0.299?(9) occupancy ratios. In both cases, the thio-phene ring is rotated by approximately 180° for the second component. Important geometrical parameters include Au-P = 2.235?(2) and 2.237?(2)?Å, Au-Cl = 2.286?(2) and 2.292?(2)?Å, and P-Au-Cl = 177.39?(8) and 172.63?(7)°. Weak inter-molecular C-H?Cl inter-actions are observed in the crystal structure.

| S-EPMC3254317 | biostudies-literature

Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]-2-(thio-phen-2-yl)ethan-amine-?P,N}platinum(II) dichloro-methane hemisolvate.

Project description:The crystal structure of the title compound, [PtCl(2)(C(25)H(22)NPS)]·0.5CH(2)Cl(2), was determined to establish the coordination properties of the (phosphan-yl)benzyl-idene-methanamine ligand to platinum. In the unit cell two mol-ecules of cis-[PtCl(2)(C(25)H(22)NPS)] are accompanied by a dichloro-methane solvent mol-ecule. The square-planar Pt(2+) coordination sphere is slightly distorted with the bidentate ligand coordinated via the P and the amine N atoms, and the Cl atoms located cis at the two remaining coordination sites. Parts of the thiophene ring and the solvate molecule were modeled as disordered with occupancy ratios of 0.55?(2):0.45?(2) and 0.302?(10):0.198?(10), respectively. Weak C-H?Cl inter-actions stabilize the crystal packing.

| S-EPMC3274858 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data