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[1,4-Bis(diphenyl-phosphan-yl)butane-?P,P']chlorido(?-inden-yl)ruthenium(II).

ABSTRACT: Facile ligand substitution is observed when the ruthenium chloride complex [Ru(?(5)-C(9)H(7))Cl(PPh(3))(2)] is treated with 1,4-bis-(diphenyl-phosphan-yl)butane in refluxing toluene yielding the title compound, [Ru(C(9)H(7))Cl(C(28)H(28)P(2))]. The Ru(II) atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502?(9) and 2.2968?(8)?Å.

SUBMITTER: Sung HL

PROVIDER: S-EPMC3089106 | biostudies-other | 2011 May

REPOSITORIES: biostudies-other

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[1,4-Bis(diphenyl-phosphan-yl)butane-κP,P']chlorido(η-inden-yl)ruthenium(II).

Sung Hui-Ling HL Her Tze-Min TM Su Wen-Hsien WH Cheng Chin-Pao CP

Acta crystallographica. Section E, Structure reports online 20110429 Pt 5

Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(PPh(3))(2)] is treated with 1,4-bis-(diphenyl-phosphan-yl)butane in refluxing toluene yielding the title compound, [Ru(C(9)H(7))Cl(C(28)H(28)P(2))]. The Ru(II) atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) Å. ...[more]

PMID: 21754349

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