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Catena-Poly[[diaqua-bis-(formato-?O)nickel(II)]-?-2,4,6-tris-(4-pyrid-yl)-1,3,5-triazine-?N:N].

ABSTRACT: In the title compound, [Ni(CHO(2))(2)(C(18)H(12)N(6))(H(2)O)(2)](n), the Ni(II) ion, lying on a crystallographic inversion center, has a distorted octa-hedral coordination comprising two water ligands, two O-atom donors from formate ligands and two N-atom donors from the 2,4,6-tris-(4-pyrid-yl)-1,3,5-triazine ligands. These ligands bridge the Ni(II) complex units, forming zigzag chains along the c axis. Adjacent chains are linked by O-H?O hydrogen bonds, forming a three-dimensional supra-molecular network.

SUBMITTER: Feng M

PROVIDER: S-EPMC3089175 | biostudies-other | 2011 May

REPOSITORIES: biostudies-other

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catena-Poly[[diaqua-bis-(formato-κO)nickel(II)]-μ-2,4,6-tris-(4-pyrid-yl)-1,3,5-triazine-κN:N].

Feng Miao M Tian Hui-Juan HJ Mi Huai-Feng HF Hu Tong-Liang TL

Acta crystallographica. Section E, Structure reports online 20110413 Pt 5

In the title compound, [Ni(CHO(2))(2)(C(18)H(12)N(6))(H(2)O)(2)](n), the Ni(II) ion, lying on a crystallographic inversion center, has a distorted octa-hedral coordination comprising two water ligands, two O-atom donors from formate ligands and two N-atom donors from the 2,4,6-tris-(4-pyrid-yl)-1,3,5-triazine ligands. These ligands bridge the Ni(II) complex units, forming zigzag chains along the c axis. Adjacent chains are linked by O-H⋯O hydrogen bonds, forming a three-dimensional supra-molecul ...[more]

PMID: 21754294

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