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Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-?N,N',N''}zinc.

ABSTRACT: In the title compound, [ZnI(2)(C(13)H(19)N(3)O)], the Zn(II) ion is five-coordinated in a distorted square-pyramidal geometry, in which the basal plane is defined by three N atoms from the Schiff base ligand and one iodide ion. A second iodide ligand, situated in the apical position, completes the coordination geometry. In the crystal structure, C-H?O hydrogen bonds link a pair of mol-ecules around an inversion centre into a dimer.

SUBMITTER: Suleiman Gwaram N

PROVIDER: S-EPMC3089331 | biostudies-other | 2011 May

REPOSITORIES: biostudies-other

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Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc.

Suleiman Gwaram Nura N Khaledi Hamid H Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20110422 Pt 5

In the title compound, [ZnI(2)(C(13)H(19)N(3)O)], the Zn(II) ion is five-coordinated in a distorted square-pyramidal geometry, in which the basal plane is defined by three N atoms from the Schiff base ligand and one iodide ion. A second iodide ligand, situated in the apical position, completes the coordination geometry. In the crystal structure, C-H⋯O hydrogen bonds link a pair of mol-ecules around an inversion centre into a dimer. ...[more]

PMID: 21754337

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