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{4-Bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolato-?S,N,O}(triphenyl-phosphane-?P)nickel(II).

ABSTRACT: The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolate ligand is 2.01?(14)°. The most prominent feature of the packing is the presence of supra-molecular chains aligned along the a axis, mediated by C-H?S inter-actions.

SUBMITTER: Tamizh MM 

PROVIDER: S-EPMC3099803 | biostudies-other | 2011 Apr

REPOSITORIES: biostudies-other

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{4-Bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolato-κS,N,O}(triphenyl-phosphane-κP)nickel(II).

Tamizh M Muthu MM   Karvembu R R   Varghese B B   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20110312 Pt 4

The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolate ligand is 2.01 (14)°. The most prominent feature of the packing is the presence of supra-molecular chains aligned along the a axis, mediated by C-H⋯S inter-actions. ...[more]

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