Browse
Submit Data
Databases
API
Help

Dataset Information

10 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis{1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-lato-?N,O}nickel(II).

ABSTRACT: In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-late ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methyl-phenyl group is 49.03?(7)°.

SUBMITTER: Wang Q

PROVIDER: S-EPMC3099807 | biostudies-other | 2011 Apr

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Bis{1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-lato-κN,O}nickel(II).

Wang Quanbo Q Jiang Jianzhuang J Zhu Peihua P

Acta crystallographica. Section E, Structure reports online 20110323 Pt 4

In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-late ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methyl-phenyl group is 49.03 (7)°. ...[more]

PMID: 21753985

Similar Datasets

Bis{1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-lato-κN,O}copper(II).

Project description:In the title complex, [Cu(C(18)H(14)NO)(2)], the Cu(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-late ligands are coordinated in a trans arrangement with respect to the N and O atoms.

| S-EPMC3008097 | biostudies-literature

Bis{1-[(E)-(2-methyl-phen-yl)diazen-yl]-2-naphtho-lato}palladium(II).

Project description:In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate methylphenyl-diazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(II) atom lies on a crystallographic inversion centre) with O-Pd-N bond angles of 89.60?(11) and 90.40?(11)°. The distances between the Pd(II) atom and the coordinated O and N atoms are 1.966?(3) and 2.009?(3)?Å, respectively.

| S-EPMC3007315 | biostudies-literature

Bis{2-[imino-(phen-yl)meth-yl]-5-meth-oxy-phenolato-?(2)N,O(1)}nickel(II).

Project description:The title complex, [Ni(C(14)H(12)NO(2))(2)], lies about an inversion center. The Ni(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and two N atoms from two 2-[imino-(phen-yl)meth-yl]-5-meth-oxy-phenolate ligands. The dihedral angle between the symmetry-unique phenyl and benzene rings is 73.2?(1)°.

| S-EPMC3515134 | biostudies-literature

Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).

Project description:The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion. The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry. The crystal packing is stabilized by N-H?O hydrogen bonds.

| S-EPMC2961174 | biostudies-literature

Bis{2-formyl-4-methyl-6-[(tri-2-pyridyl-meth-yl)imino-meth-yl]phenolato}nickel(II).

Project description:The title compound, [Ni(C(25)H(19)N(4)O(2))(2)], which was obtained by the reaction of nickel(II) perchlorate with 2,6-diformyl-4-methyl-phenol and (tri-2-pyridylmeth-yl)amine in methanol solution, is a discrete monometallic complex. The Ni(II) atom is six-coordinated by the phenolate O, imine N and pyridine N atoms from two tridentate Schiff base ligands in a distorted NiN(4)O(2) octa-hedral geometry. The dihedral angles between the noncoordinated pyridyl rings of each ligand are 72.95?(8) and 69.59?(7)°.

| S-EPMC2968412 | biostudies-literature

Bis{?-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}bis-({2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}copper(II)).

Project description:The title compound, [Cu2(C9H10NO2)4], is built of discrete centrosymmetric dimers. The Cu(II) atoms are each five coordinated by two deprotonated Schiff base ligands that are bonded differently to the metal atoms. Of the two phenolate O atoms, one is coordinated to one Cu(II) atom, whereas another bridges the two metal atoms. The basal plane of the square pyramid around Cu(II) atoms is formed by the imino N and phenolate O atoms of the bidentate and the monodentate/bidentate Schiff base ligands. The bridging phenolate oxygen occupies the apical position of the coordination sphere with a considerably longer Cu-O bond length. In the crystal, the dimeric mol-ecules pack relative to each other in such a way that the Cu2O2 planes of adjacent dimers are orthogonal.

| S-EPMC3790358 | biostudies-literature

cis-Bis{(E)-2-[(2-fluoro-phen-yl)imino-meth-yl]phenolato-?(2) N,O}bis-(pyridine-?N)nickel(II).

Project description:The structure of the title compound, [Ni(C13H9FNO)2(C5H5N)2], consists of an Ni(II) atom on a crystallographic center of symmetry, octa-hedrally bonded through both the N and O atoms to two 2-[(2-fluoro-phen-yl)imino-meth-yl]phenolate (L) ligands, as well as two pyridine ligands. The F atoms of L are disordered over two positions related by a 180° rotation of the fluoro-phenyl group around its external C-N bond.

| S-EPMC3588732 | biostudies-literature

Bis{2-[(E)-benzyl-imino-meth-yl]-4-methyl-phen-olato-?N,O}cobalt(II).

Project description:In the title complex, [Co(C(15)H(14)NO)(2)], the Co(II) atom, situated on an inversion centre, is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a slightly distorted square-planar geometry. The two phenolate rings form a dihedral angle of 10.53?(2)°.

| S-EPMC2960051 | biostudies-literature

Bis[2-(3-cyano-phenyl-imino-meth-yl)phenolato]nickel(II).

Project description:In the title complex, [Ni(C(14)H(9)N(2)O)(2)], the Ni(II) atom lies on an inversion center and is coordinated by the O atom and an N atom of two Schiff base 2-(3-cyano-phenyl-imino-meth-yl)phenolate ligands in a square-planar geometry. The dihedral angle between the cyano-phenyl and phenolate rings is 47.62?(7)°.

| S-EPMC2960771 | biostudies-literature

Di-?-chlorido-bis-{chlorido[2-(2-furyl-methyl-imino-meth-yl)pyridine-?N,N']nickel(II)}.

Project description:The title dinuclear nickel(II) complex, [Ni(2)Cl(4)(C(11)H(10)N(2)O)(2)], lies on a centre of symmetry located at the centroid of the four-membered ring formed by the two Ni atoms and the bridging chloride ions. The Ni(II) atom is five-coordinated in a square-pyramidal geometry by the imine and pyridine N atoms of the Schiff base ligand, and by one terminal and two bridging Cl atoms. The Ni?Ni distance is 3.506?(2)?Å. The O atom of the furan substituent in the ligand unit is not involved in coordination to the Ni atom.

| S-EPMC2961345 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data