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Bis{1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-lato-?N,O}nickel(II).

ABSTRACT: In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-late ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methyl-phenyl group is 49.03?(7)°.

SUBMITTER: Wang Q

PROVIDER: S-EPMC3099807 | biostudies-other | 2011 Apr

REPOSITORIES: biostudies-other

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Bis{1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-lato-κN,O}nickel(II).

Wang Quanbo Q Jiang Jianzhuang J Zhu Peihua P

Acta crystallographica. Section E, Structure reports online 20110323 Pt 4

In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-late ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methyl-phenyl group is 49.03 (7)°. ...[more]

PMID: 21753985

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