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(Acetato-?O)bis-(1,10-phenanthroline-?N,N')copper(II) acetate hepta-hydrate.

ABSTRACT: In the title complex, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CH(3)CO(2))·7H(2)O, the central Cu(II) ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water mol-ecules and an uncoordinated acetate anion form a two-dimensional polymeric structure parallel to (010). The cations are linked to this layer via O-H?O hydrogen bonds between one of the water mol-ecules and the coordinated acetate anion.

SUBMITTER: Jing B

PROVIDER: S-EPMC3099845 | biostudies-other | 2011 Apr

REPOSITORIES: biostudies-other

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(Acetato-κO)bis-(1,10-phenanthroline-κN,N')copper(II) acetate hepta-hydrate.

Jing Buqin B Li Lianzhi L Dong Jianfang J Xu Tao T

Acta crystallographica. Section E, Structure reports online 20110319 Pt 4

In the title complex, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CH(3)CO(2))·7H(2)O, the central Cu(II) ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water mol-ecules and an uncoordinated acetate anion form a two-dimensional polymeric structure parallel to (010). The cations are linked to this layer via O-H⋯O hydrogen bonds between one of the water mol-e ...[more]

PMID: 21753980

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Bis(1,10-phenanthroline-?N,N')(phenyl-acetato-?O)copper(II) phenyl-acetate hexa-hydrate.

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